When I was involved in designing and building optical instruments (professionally) one of the down sides of most of the high performance surface materials requiring coating is that they would start to oxidize 'sideways' from any nick, scratch or imperfection in the coating. Usually acceptable in an instrument you take really good care of or internal surfaces, but not so good on the 'outer' surface or anything exposed to wear.
As Tobin said, more robust but slightly less reflective materials like nickle are often preferred for those surfaces. But practically speaking for this application, IIRC you're talking about the difference between 98+% reflectivity and 99+%. In other words, not a terribly significant advantage. You loose more if the mirror is worn, scratched or has some goop or salt on it. You're probably better off with something scratch resistant, which dirt, salt and water doesn't like to stick to, and which doesn't oxidize much, especially around salt, which I guess brings us back to the original question of this thread.
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